Unregulated flame retardants can break down into toxic byproducts, study shows
By Douglas Main
New research shows that two unregulated and widely used flame retardants found in many electronic devices and touted by industry as non-toxic break down into harmful molecules that can pose a health risk to fish and potentially other creatures, including humans.
The chemicals in question, large molecules called polymers, have largely escaped regulation as industry has argued that the materials are unlikely to degrade or make their way into living creatures. Many are even marketed as non-hazardous or environmentally friendly.
But a study published Monday in the journal Nature Sustainability found evidence suggesting that is not true. Researchers reported finding dozens of smaller molecules caused by the breakdown of polymeric flame retardants in soil, dust, and air outside electronic waste recycling facilities in southern China. The scientists exposed zebrafish — commonly used in initial toxicity tests — to the chemicals and found that they caused metabolic dysfunction and showed the potential for development harm.
“Our study suggests polymers can act as a trojan horse for toxic chemicals,” Da Chen, senior author and scientist at Jinan University in China. “They are added to products as inert large molecules, but over time they can degrade, exposing us to their harmful breakdown products.”
In recent years, polymeric flame retardants have been used to replace smaller, toxic molecules, such as chemicals called HBCD and PBDE, which have been partially phased out due to safety concerns.
Most polymers, including all such flame retardants, are considered exempt from major regulations meant to protect humans. But the new research shows regulation is needed, said Arlene Blum, co-author of the study and a research associate at the University of California, Berkeley. Blum also serves as executive director of the Green Science Policy Institute.